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- W2035405943 abstract "Abstract The synthesis, chemical characterisation and single crystal X-ray structural study of the bis-toluene hexaruthenium carbidocarbonyl cluster [Ru 6 C(CO) 11 (η 6 C 6 H 5 Me)(μ 3 -η 2 : η 2 : η 2 -C 6 H 5 Me)] is reported. A variable temperature 1 H n.m.r. study reveals that in solution the complex exists in two isomeric forms, one of them, that observed in the solid state and the other the trans -[Ru 6 C(CO) 11 ](η 6 -C 6 H 5 Me) 2 ] isomer. Interchange of the toluene ligand between the μ 3 -η 2 : η 2 : η 2 and η 6 co-ordination mode if confirmed by deuterum labelling experiments involving C 6 D 5 CD 3 ." @default.
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- W2035405943 date "1993-12-01" @default.
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- W2035405943 title "The synthesis, structural characterisation and variable temperature 1H NMR study of the bis-toluene hexaruthenium carbidocarbonyl cluster [Ru6C(CO)11(η6C6H5Me)(μ3-η2: η2: η2-C6H5Me)]" @default.
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- W2035405943 doi "https://doi.org/10.1016/0022-328x(93)83371-2" @default.
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