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- W2035426608 abstract "We have investigated the vibrational properties of cyanide and thiocyanate ions adsorbed on a platinum electrode in sodium perchlorate supporting electrolyte using the non-linear optical technique of sum frequency generation (SFG). Two bands were observed for the stretching vibration modes of both CN− and SCN− ions. The first band, which appears at −1 V for both ions at ca 2070 cm−1 with a large potential tuning rate, has been attributed to N-bound adsorbed CN− or SCN−. The second band appears at −0.2 V during the positive potential scan. It is in antiphase with the first one and is localized around 2150 cm− for CN− and 2140 cm− for SCN−. It has a smaller potential tuning rate. We have assigned it to C-bound adsorbed CN− and S-bound adsorbed SCN−. Both bands are present as long as the electrode potential is scanned within the −1 V + 0.5 V/sce range forming, to some extent, a cyanide or a thiocyanate bilayer on the surface. The great potential tuning rate difference between the two bands suggests a great difference in the adsorption processes, the N-bound species being more tightly chemisorbed at the platinum electrode. SFG therefore appears to be a powerful technique to probe the vibrational properties of adsorbed species at each electrode potential." @default.
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- W2035426608 date "1991-01-01" @default.
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- W2035426608 title "Spectroscopic investigation of adsorbed cyanide and thiocyanate on platinum using sum frequency generation" @default.
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- W2035426608 doi "https://doi.org/10.1016/0013-4686(91)85055-c" @default.
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