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• W2035442264 endingPage "10634" @default.
• W2035442264 startingPage "10630" @default.
• W2035442264 abstract "Monte Carlo simulation and the modified Poisson−Boltzmann theory are used to investigate the planar electric double layer for a restricted primitive model electrolyte at low temperatures. Capacitance as a function of temperature at low surface charge is determined for 1:1, 2:2, 2:1, and 3:1 electrolytes. Negative adsorption can occur for 1:1 electrolytes at low surface charge with low electrolyte concentration. The 1:1 electrolyte diffuse layer potential as a function of surface charge displays a maximum at low densities. At high densities, the diffuse layer potential is negative with a negative slope. The Gouy−Chapman−Stern theory fails in this low-temperature regime, whereas the modified Poisson−Boltzmann theory is fairly successful in this regard." @default.
• W2035442264 created "2016-06-24" @default.
• W2035442264 creator A5020101668 @default.
• W2035442264 creator A5061739405 @default.
• W2035442264 creator A5076068321 @default.
• W2035442264 date "2006-05-18" @default.
• W2035442264 modified "2023-09-30" @default.
• W2035442264 title "Planar Electric Double Layer for a Restricted Primitive Model Electrolyte at Low Temperatures" @default.
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• W2035442264 doi "https://doi.org/10.1021/la060425k" @default.
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