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- W2035442318 abstract "An efficient synthesis of an ammonium tagged carbapalladacycle 5, in modest yield, has been achieved. Further, the clay-nanocomposite 6 was prepared by ion exchange of 5 into clay interlayers as a new organic–inorganic hybrid catalytic system. The ionic tag of the ammonium supported carbapalladacycle 5 assists in the pillaring process and enhances the organophilicity of catalyst 6 in the interlayers of clay. The catalytic activity in ammonium based ionic liquid [TMBA] NTf2 of both the homogeneous and heterogeneous recyclable catalysts 5 and 6 respectively in micromolar concentration of palladium has been tested for Mizoroki–Heck and Sonogashira reactions in good yields with high TON/TOF and negligible metal leaching. Effect of solvent and temperature on the catalytic activity has also been examined." @default.
- W2035442318 created "2016-06-24" @default.
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- W2035442318 date "2011-01-01" @default.
- W2035442318 modified "2023-10-16" @default.
- W2035442318 title "Synthesis and characterization of recyclable and recoverable MMT-clay exchanged ammonium tagged carbapalladacycle catalyst for Mizoroki–Heck and Sonogashira reactions in ionic liquid media" @default.
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- W2035442318 doi "https://doi.org/10.1016/j.molcata.2010.10.015" @default.
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