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- W2035442339 abstract "Abstract Intermolecular interactions of merocyanine dyes, 5-[2-(3-ethyl-2-benzothiazolylidene)-1-methyl-ethylidene]-3-ethyl-2-thioxo-4-thiazolidinone (Et(Me)MD) and 5-[2-(3-ethyl-2-benzothiazolylidene)-ethylidene]-3-ethyl-2-thioxo-4-thiazolidinone (EtMD), in various solvents were studied. The spectra of the dyes in an argon matrix-isolated state and in a thin-film state were also measured. In addition to the well-known solvent effects appearing in visible absorption spectra, the solvent dependence of resonance Raman and infrared absorption spectra was examined. The visible absorption bands shift to the longer wavelength region as the polarity of the solvent increases, while the CO and CC stretching bands shift to the lower frequency region. Correlation between the visible absorption maximum and the CC stretching vibrational frequency was found, for the first time. The solvent effects on the spectra are explained in terms of intermolecular interactions between merocyanine dyes and solvent molecules." @default.
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- W2035442339 date "1997-05-01" @default.
- W2035442339 modified "2023-09-30" @default.
- W2035442339 title "Intermolecular interactions of merocyanine dyes studied by visible absorption, resonance Raman and infrared spectroscopies" @default.
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- W2035442339 doi "https://doi.org/10.1016/s0022-2860(96)09735-9" @default.
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