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• W2035447375 endingPage "1248" @default.
• W2035447375 startingPage "1240" @default.
• W2035447375 abstract "Investigation of scandium incorporation in garnets along the synthetic Ca3Fe23+Si3O12-Ca3Sc2Si3O12 (adr.CaSc) join, based on the same multi-technique approach used in the companion paper (Oberti et al. 2006a), shows that (1) Sc is incorporated exclusively at the Y octahedron; (2) the local coordination of Sc is slightly different in Sc-poor than in Sc-rich compositions (Sc-O = 2.06 Å in CaSc10 vs. 2.10 Å in CaSc30-90); (3) the local coordination of Ca is also slightly different in Sc-poor than in Sc-rich compositions [Ca1,2-O are 2.34(2) and 2.48(2) Å in CaSc10 and 2.36(2) and 2.50(2) Å in CaSc90, with Δ fixed at 0.14 Å in all the samples]; (4) the linear increase of the unit-cell edge along the join derives from multiple changes in the geometry of the different polyhedra and from the rotation of the tetrahedron around the 4̄ axis (α rotation), and cannot be modeled from extrapolation of the behavior observed along the Ca3Al2Si3O12-Ca3Fe23+Si3O12 (grs.adr) join." @default.
• W2035447375 created "2016-06-24" @default.
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• W2035447375 date "2006-08-01" @default.
• W2035447375 modified "2023-10-07" @default.
• W2035447375 title "Site preference and local geometry of Sc in garnets: Part II. The crystal-chemistry of octahedral Sc in the andradite-Ca3Sc2Si3O12 join" @default.
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• W2035447375 doi "https://doi.org/10.2138/am.2006.2038" @default.
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