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- W2035448458 abstract "Abstract We report in-situ extended X-ray absorption fine-structure (EXAFS) studies of icosahedral Al6Li3Cu quasicrystals, without any aluminium excess, under a high pressure in quasihydrostatic conditions. The EXAFS experiments have been performed at the Cu K absorption edge from ambient pressure up to 33 GPa and give the variation in the average distance of fist neighbours around copper atoms against pressure. This average distance decreases monotonically with increasing pressure up to 12 GPa, remains almost constant up to 20 GPa and then increases. This increase in the interatomic distance is interpreted as the fingerprint of a phase transition. The relative first-neighbour distance has been fitted, up to 12 GPa, by a Murnaghan equation of state so that the zero-pressure bulk modulus is B 0 = 71 GPa for a first derivative B′0 = 6. This B 0 local value found around copper atoms is close to the overall bulk modulus of pure aluminium. After release of the pressure, the Al6Li3Cu quasicrystal shows spectacular 'metastable' properties." @default.
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- W2035448458 date "1996-09-01" @default.
- W2035448458 modified "2023-10-18" @default.
- W2035448458 title "Pressure-induced phase transition in icosahedral Al–Li–Cu quasicrystals" @default.
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- W2035448458 doi "https://doi.org/10.1080/01418619608243532" @default.
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