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- W2035465048 abstract "The origin of a prominent [M – CH3] ion in the mass spectrum of 2,3,4,5-tetrahydrobenzoxepin is investigated with the aid of extensive deuterium labelling of the saturated heterocyclic portion of the molecule, identifying the C-2 methylene group as the chief source of the methyl radical expelled. Ring contraction of the seven-membered cyclic molecular ion to a six-membered intermediate is proposed in accordance with interpretations of similar findings on related acylated cyclic amines." @default.
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- W2035465048 date "1973-04-01" @default.
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- W2035465048 title "Ring contraction upon electron-impact as a function of ring size: The mass spectrometric fragmentation of 2,3,4,5-tetrahydrobenzoxepin and lower homologues" @default.
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- W2035465048 doi "https://doi.org/10.1002/oms.1210070412" @default.
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