Matches in SemOpenAlex for { <https://semopenalex.org/work/W2035467364> ?p ?o ?g. }
- W2035467364 endingPage "2218" @default.
- W2035467364 startingPage "2214" @default.
- W2035467364 abstract "We developed a highly efficient palladium-catalyzed three-component tandem carbofluorination of allenes with ArI and AgF. Nucleophilic trapping of π-allyl palladium intermediates generated from carbopalladation of allenes with AgF delivers functionalized allylic fluorides with highly branched selectivity. This transformation features simultaneous construction of C–C and C–F bond in one step, allowing for the facile synthesis of functionalized allylic fluorides, valuable synthetic building blocks. Moreover, a good correlation between regioselectivity and substituent Hammett constants was observed in the reactions of mono-alkyl substituted allene substrates, corroborating with the proposed outer-sphere fluorination pathway. This study uncovered the regioselectivity trends being controlled by both electronic and steric factors, which paved the way for further developments in selective synthesis of branched functionalized allylic fluorides difficult to access from established methodologies." @default.
- W2035467364 created "2016-06-24" @default.
- W2035467364 creator A5005303316 @default.
- W2035467364 creator A5035752387 @default.
- W2035467364 creator A5063937330 @default.
- W2035467364 date "2015-04-01" @default.
- W2035467364 modified "2023-10-16" @default.
- W2035467364 title "Regio- and stereoselective synthesis of functionalized allylic fluorides via palladium-catalyzed three-component tandem carbofluorination of allenes" @default.
- W2035467364 cites W1966686785 @default.
- W2035467364 cites W2001086298 @default.
- W2035467364 cites W2007224999 @default.
- W2035467364 cites W2012404887 @default.
- W2035467364 cites W2015981085 @default.
- W2035467364 cites W2016288905 @default.
- W2035467364 cites W2032668817 @default.
- W2035467364 cites W2034285345 @default.
- W2035467364 cites W2045942454 @default.
- W2035467364 cites W2053232718 @default.
- W2035467364 cites W2078248816 @default.
- W2035467364 cites W2087676073 @default.
- W2035467364 cites W2087717620 @default.
- W2035467364 cites W2094065729 @default.
- W2035467364 cites W2097510608 @default.
- W2035467364 cites W2102624356 @default.
- W2035467364 cites W2103380929 @default.
- W2035467364 cites W2116087305 @default.
- W2035467364 cites W2116166338 @default.
- W2035467364 cites W2138484542 @default.
- W2035467364 cites W2144885598 @default.
- W2035467364 cites W2157298675 @default.
- W2035467364 cites W2159670464 @default.
- W2035467364 cites W2166302982 @default.
- W2035467364 cites W2325094167 @default.
- W2035467364 cites W2329735764 @default.
- W2035467364 cites W2333129245 @default.
- W2035467364 cites W2953134480 @default.
- W2035467364 cites W4237683331 @default.
- W2035467364 cites W593240817 @default.
- W2035467364 doi "https://doi.org/10.1016/j.tetlet.2015.03.028" @default.
- W2035467364 hasPublicationYear "2015" @default.
- W2035467364 type Work @default.
- W2035467364 sameAs 2035467364 @default.
- W2035467364 citedByCount "9" @default.
- W2035467364 countsByYear W20354673642015 @default.
- W2035467364 countsByYear W20354673642018 @default.
- W2035467364 countsByYear W20354673642020 @default.
- W2035467364 countsByYear W20354673642021 @default.
- W2035467364 countsByYear W20354673642022 @default.
- W2035467364 countsByYear W20354673642023 @default.
- W2035467364 crossrefType "journal-article" @default.
- W2035467364 hasAuthorship W2035467364A5005303316 @default.
- W2035467364 hasAuthorship W2035467364A5035752387 @default.
- W2035467364 hasAuthorship W2035467364A5063937330 @default.
- W2035467364 hasConcept C120095180 @default.
- W2035467364 hasConcept C155647269 @default.
- W2035467364 hasConcept C159985019 @default.
- W2035467364 hasConcept C161790260 @default.
- W2035467364 hasConcept C178790620 @default.
- W2035467364 hasConcept C178907741 @default.
- W2035467364 hasConcept C181647583 @default.
- W2035467364 hasConcept C185592680 @default.
- W2035467364 hasConcept C192562407 @default.
- W2035467364 hasConcept C201194858 @default.
- W2035467364 hasConcept C21951064 @default.
- W2035467364 hasConcept C2777814067 @default.
- W2035467364 hasConcept C2778652500 @default.
- W2035467364 hasConcept C2778689049 @default.
- W2035467364 hasConcept C2780263894 @default.
- W2035467364 hasConcept C502130503 @default.
- W2035467364 hasConcept C58548122 @default.
- W2035467364 hasConcept C59759590 @default.
- W2035467364 hasConcept C71240020 @default.
- W2035467364 hasConceptScore W2035467364C120095180 @default.
- W2035467364 hasConceptScore W2035467364C155647269 @default.
- W2035467364 hasConceptScore W2035467364C159985019 @default.
- W2035467364 hasConceptScore W2035467364C161790260 @default.
- W2035467364 hasConceptScore W2035467364C178790620 @default.
- W2035467364 hasConceptScore W2035467364C178907741 @default.
- W2035467364 hasConceptScore W2035467364C181647583 @default.
- W2035467364 hasConceptScore W2035467364C185592680 @default.
- W2035467364 hasConceptScore W2035467364C192562407 @default.
- W2035467364 hasConceptScore W2035467364C201194858 @default.
- W2035467364 hasConceptScore W2035467364C21951064 @default.
- W2035467364 hasConceptScore W2035467364C2777814067 @default.
- W2035467364 hasConceptScore W2035467364C2778652500 @default.
- W2035467364 hasConceptScore W2035467364C2778689049 @default.
- W2035467364 hasConceptScore W2035467364C2780263894 @default.
- W2035467364 hasConceptScore W2035467364C502130503 @default.
- W2035467364 hasConceptScore W2035467364C58548122 @default.
- W2035467364 hasConceptScore W2035467364C59759590 @default.
- W2035467364 hasConceptScore W2035467364C71240020 @default.
- W2035467364 hasFunder F4320313888 @default.
- W2035467364 hasFunder F4320321001 @default.
- W2035467364 hasIssue "17" @default.
- W2035467364 hasLocation W20354673641 @default.
- W2035467364 hasOpenAccess W2035467364 @default.
- W2035467364 hasPrimaryLocation W20354673641 @default.
- W2035467364 hasRelatedWork W1973868118 @default.