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• W2035480523 abstract "Di-tert-butylnitroxide (DTBN) is the simplest of the stable nitroxide radicals and is only consumed at temperatures higher than 90°C or in the presence of very reactive substrates. The pyrolysis of DTBN in solution gives, at least at low conversion, 2-methyl-2-nitrosopropane and di-tert-butylnitroxide-tert-butyl ether. The reaction involves, as the rate-limiting step, the cleavage of the CN bond. This reaction takes place with an activation energy of 33 kcal/mol. DTBN is stable in the presence of styrene, aldehydes, hydrogen peroxide, α-methyl-N-ethyl nitrone, phenol, and triphenylmethane. On the other hand, it reacts readily with diethylhydroxylamine, ascorbid acid, ethanethiol, and hexanethiol. For the two former compounds the reaction involves a hydrogen transfer as the rate-determining step, and the reaction proceeds, a low conversion, with simple second-order kinetics. The reaction with the thiols is complex and shows a clear inductiontime." @default.
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• W2035480523 date "1980-11-01" @default.
• W2035480523 modified "2023-10-03" @default.
• W2035480523 title "Reaction of di-tert-butylnitroxide radicals" @default.
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• W2035480523 doi "https://doi.org/10.1002/kin.550121106" @default.
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