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- W2035491142 abstract "Abstract The effectiveness of NH 3 gas used in a Dynamic Reaction Cell (DRC) in reducing or eliminating carbon-based polyatomic ions in electrothermal vaporization (ETV) inductively coupled plasma mass spectrometry is reported. Ammonia gas was found effective in reducing interfering polyatomic ions on both Cr and Mg isotope ions. The use of NH 3 as a reaction gas for the reduction of polyatomic ion interferences on Si was not fully successful. However, the LODs for 28 Si + and 29 Si + were greatly improved over conventional ICP-MS. Ammonia was found to be unsuitable as a reaction gas for the determination of 30 Si + . Results of signal to background studies indicate that the experimental conditions required to optimize the DRC were close for solution nebulization and ETV for Cr only. For Mg and Si, different optimization conditions were required." @default.
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- W2035491142 date "2003-02-01" @default.
- W2035491142 modified "2023-09-27" @default.
- W2035491142 title "Effectiveness of ammonia in reducing carbon-based polyatomic ion interferences in electrothermal vaporization collision cell inductively coupled plasma mass spectrometry" @default.
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- W2035491142 doi "https://doi.org/10.1016/s0584-8547(02)00149-0" @default.
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