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• W2035492280 abstract "Abstract The incompressible lattice‐gas model by ten Brinke and Karasz is adopted to introduce the effect of specific interactions into a recently‐presented Monte‐Carlobased lattice expression for the Helmholtz energy of nonrandom mixing. While the lattice remains incompressible, intermolecular forces consist of two types: London dispersion forces and specific (chemical) forces. The specific interactions between similar components, as well as those between dissimilar components, are incorporated in a systematic manner. Closed‐loop temperature‐composition phase diagrams are obtained. The theory is compared with experimental data for several binary systems, including polymer solutions, which exhibit closed‐loop coexistence curves. Theoretical and experimental results are in good agreement." @default.
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• W2035492280 date "1993-05-01" @default.
• W2035492280 modified "2023-10-17" @default.
• W2035492280 title "Lattice thermodynamics for binary closed‐loop equilibria: Ordinary and polymer systems" @default.
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• W2035492280 doi "https://doi.org/10.1002/aic.690390512" @default.
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