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- W2035500349 abstract "Ti-containing mesoporous catalysts with MCM-41 structure have been successfully prepared by direct hydrothermal synthesis. These mesoporous materials were compared with pure siliceous MCM-41 synthesized at the same conditions. An extended and detailed study, which includes the effects of several factors such as the state and content of Ti, surfactant/Si ratio and template removal technique on the physicochemical properties and catalytic activity of Ti-MCM-41, is presented in this contribution. Various techniques including XRD, FT-IR, DRUV–vis, ICP and N2 adsorption were employed for the materials characterization. An optimum surfactant/Si molar ratio in the synthesis gel for the highest regularity of the formed mesostructure was found. Both the structure stability and the local environment of Ti sites in mesostructures with different degrees of Ti loading (0.10–3.22 wt.%) have been carefully investigated. Based on a combined FT-IR and DRUV–vis study and ICP analysis, it was possible to conclude that Infrared spectroscopy can result a powerful tool to verify the Ti(IV) incorporation into the framework of MCM-41. Therefore, a simple and novel method for estimation of framework Ti content could be developed. Also, these materials were catalytically tested in the oxidation of cyclohexene with aqueous hydrogen peroxide. Finally, the catalysts could be regenerated without any loss in activity/selectivity." @default.
- W2035500349 created "2016-06-24" @default.
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- W2035500349 date "2006-01-10" @default.
- W2035500349 modified "2023-10-16" @default.
- W2035500349 title "Synthesis, characterization and selective oxidation properties of Ti-containing mesoporous catalysts" @default.
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- W2035500349 cites W1963693075 @default.
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- W2035500349 cites W1967414080 @default.
- W2035500349 cites W1968944261 @default.
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- W2035500349 cites W1974541812 @default.
- W2035500349 cites W1977477072 @default.
- W2035500349 cites W1978602528 @default.
- W2035500349 cites W1982784029 @default.
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- W2035500349 cites W1997188366 @default.
- W2035500349 cites W1998669213 @default.
- W2035500349 cites W1999755245 @default.
- W2035500349 cites W2000791775 @default.
- W2035500349 cites W2006342691 @default.
- W2035500349 cites W2009971052 @default.
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- W2035500349 cites W2013496310 @default.
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- W2035500349 doi "https://doi.org/10.1016/j.apcata.2005.10.006" @default.
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