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- W2035530922 abstract "Abstract Tricyanomethanid schließt sich in seinem komplexchemischen Verhalten weitgehend dem der Halogenide und Pseudohalogenide (NCS, SR) an. Nitrosyltricyanomethanide von Kobalt und Nickel, [Co(NO) 2 C(CN) 3 ] n und [Ni(NO)C(CN) 3 ] n , werden durch Umsetzung der entsprechenden Nitrosylhalogenide mit Kaliumtricyanomethanid erhalten. [Co(NO) 2 C(CN) 3 ] n und [Ni(NO)C(CN) 3 ] n reagieren mit tertiären Phosphinen unter Bildung von Komplexverbindungen des Typs Co(NO) 2 LNCC(CN) 2 , Ni(NO)L 2 NCC(CN) 2 und [Ni(NO)LC(CN) 3 ] n (L = P(C 6 H 5 ) 3 , P(C 6 H 11 ) 3 , 1/2(C 6 H 5 ) 2 PCH 2 CH 2 P(C 6 H 5 ) 2 ). Während in den monomeren Verbindungen Metall–NCC(CN) 2 ‐Bindungen anzunehmen sind, werden für die mehrkernigen Komplexe Strukturen mit Tricyanomethanid‐Brücken vorgeschlagen." @default.
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- W2035530922 date "1966-06-01" @default.
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- W2035530922 title "Über Metall‐Stickoxid‐Komplexe. XXI. Tricyanomethanido–Nitrosyl‐Komplexe von Kobalt und Nickel" @default.
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- W2035530922 doi "https://doi.org/10.1002/zaac.19663440508" @default.
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