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- W2035536447 abstract "Alkali metaborate monomer and dimer vapors have been studied thermodynamically, and these results have been compared with those for alkali halides. The ratios of mean dissociation energies for one M-BO2 bond in the M2(BO2)2(g) dimers to dissociation energies for one M-BO2 bond in the MBO2(g) monomers are almost constant for all the alkali metals (M) and an average value is 0.63±0.01. This value is just equal to the corresponding ratios for halides. For the dimerization reactions of MBO2(g), both free energies and enthalpies decrease in going from M=Li to M=Cs, while entropies are almost constant. A similar tendency can be seen in chlorides. For the alkali-alkali exchange reactions in the dimers, free energies, enthalpies, and entropies are very small for both metaborates and chlorides. Excess stabilities in the alkali-alkali mixed-dimer formations are explained from the correlation with the increases in the alkali cation-cation repulsion energies." @default.
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- W2035536447 date "1992-01-01" @default.
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- W2035536447 title "Thermodynamic Quantities for Reactions of Alkali Metaborate Monomer and Dimer Vapors." @default.
- W2035536447 doi "https://doi.org/10.5702/massspec.40.9" @default.
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