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• W2035537551 endingPage "872" @default.
• W2035537551 startingPage "865" @default.
• W2035537551 abstract "Solvation structures of the lithium cation and tetrafluorobrate anion in dimethyl sulfoxide (DMSO) were investigated by Raman spectroscopy and ab initio calculations at various salt concentrations. The SO and CS stretching bands were used to monitor the structural change of the solvation shell. It has been shown that the solvation number of Li+, calculated by the changes in intensities of the CS asymmetric and symmetric stretching bands, is consistent with the value predicted by ab initio calculations. The wavenumber shift of the CH stretching band is suggested to be the result of the anion solvation and the dissociation of the associated DMSO molecules. Copyright © 2007 John Wiley & Sons, Ltd." @default.
• W2035537551 created "2016-06-24" @default.
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• W2035537551 date "2007-01-01" @default.
• W2035537551 modified "2023-10-05" @default.
• W2035537551 title "Experimental and computational studies on the solvation of lithium tetrafluorobrate in dimethyl sulfoxide" @default.
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• W2035537551 doi "https://doi.org/10.1002/jrs.1732" @default.
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