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- W2035589344 abstract "The intermediates and the mechanism of the SCR reaction of NO with NH3 on TiO2 sulfate have been studied by Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS), FT-IR and NH3-TPD. In the presence of ammonia on the surface, NO adsorbed as NO− species are enhanced and then oxidized to NO2 and NO3− by oxygen either from structure or NO. The formation of NO3− species perturbs the adsorption of protonated ammonia and induces its removal as N2 at 300°C. The result obtained from FT-IR shows that the NH3 species adsorbed on Lewis acid site remain as main species at high temperature. Accordingly, a Langmuir–Hinshelwood mechanism on Lewis acid site is suggested." @default.
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- W2035589344 date "2000-06-01" @default.
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- W2035589344 title "The investigation of mechanism of SCR reaction on a TiO2-SO42− catalyst by DRIFTS" @default.
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- W2035589344 doi "https://doi.org/10.1016/s0926-3373(00)00145-4" @default.
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