FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2035610206> ?p ?o ?g. }

• W2035610206 abstract "This contribution aims to elucidate the connection between ion-ion-solvent interactions in the bulk of aqueous electrolyte solutions and the properties of their liquid-air interface. In particular, we were interested in the conditions under which ion pairs form at the surface and whether this is linked to ion pairing in the bulk. For this reason different combinations of hard (Cl−, Li+) and soft ions (I−, Cs+) were investigated. Ion hydration and possible ion association in the bulk was probed with dielectric relaxation spectroscopy. This technique monitors the cooperative reorientation of the dipolar solvent molecules and detects all ion-pair species possibly present in the solution. At the interface, the formation of contact ion pairs was investigated by infrared-visible-sum frequency spectroscopy (SFG). This nonlinear optical technique possesses an inherent surface specificity and can be used for the characterization of interfacial water. The intensity of the SFG-active vibrational stretching modes depends on the number of oriented water molecules. The electric field at the surface of a charged aqueous interface aligns the water dipoles, which in turn increases the SFG response. Hence, the enhancement of the oscillator strengths of the water vibrational modes can be used to draw some conclusions on the strengths and geometrical extension of the electric field. The formation of ion pairs at the interface reduces the intensity of the band associated with hydrogen-bonded water. The underlying theory is presented. The combined data show that there are no contact ion pairs in the bulk of the fluid and—at best—only small amounts of solvent shared ion pairs. On the other hand, the combination of hard/hard or soft/soft ions leads to the formation of ion pairs at the liquid-air interface." @default.
• W2035610206 created "2016-06-24" @default.
• W2035610206 creator A5025014125 @default.
• W2035610206 creator A5052271356 @default.
• W2035610206 creator A5063060133 @default.
• W2035610206 creator A5063193867 @default.
• W2035610206 creator A5067099296 @default.
• W2035610206 date "2014-09-22" @default.
• W2035610206 modified "2023-10-14" @default.
• W2035610206 title "Is surface layering of aqueous alkali halides determined by ion pairing in the bulk solution?" @default.
• W2035610206 cites W1565828699 @default.
• W2035610206 cites W1866081134 @default.
• W2035610206 cites W1965224491 @default.
• W2035610206 cites W1967746790 @default.
• W2035610206 cites W1972175237 @default.
• W2035610206 cites W1973506949 @default.
• W2035610206 cites W1974558433 @default.
• W2035610206 cites W1979538248 @default.
• W2035610206 cites W1981696528 @default.
• W2035610206 cites W1984498082 @default.
• W2035610206 cites W1988904825 @default.
• W2035610206 cites W1991163974 @default.
• W2035610206 cites W1995968473 @default.
• W2035610206 cites W1996690237 @default.
• W2035610206 cites W1998727267 @default.
• W2035610206 cites W2000827899 @default.
• W2035610206 cites W2003740295 @default.
• W2035610206 cites W2004865334 @default.
• W2035610206 cites W2012325954 @default.
• W2035610206 cites W2013107255 @default.
• W2035610206 cites W2014395371 @default.
• W2035610206 cites W2014746383 @default.
• W2035610206 cites W2015898008 @default.
• W2035610206 cites W2021157842 @default.
• W2035610206 cites W2034795511 @default.
• W2035610206 cites W2039551821 @default.
• W2035610206 cites W2042031013 @default.
• W2035610206 cites W2044674089 @default.
• W2035610206 cites W2048255344 @default.
• W2035610206 cites W2050676282 @default.
• W2035610206 cites W2052655087 @default.
• W2035610206 cites W2054876894 @default.
• W2035610206 cites W2055333997 @default.
• W2035610206 cites W2056689680 @default.
• W2035610206 cites W2058197625 @default.
• W2035610206 cites W2062932567 @default.
• W2035610206 cites W2065377007 @default.
• W2035610206 cites W2065959149 @default.
• W2035610206 cites W2070136243 @default.
• W2035610206 cites W2075320109 @default.
• W2035610206 cites W2082234179 @default.
• W2035610206 cites W2084128514 @default.
• W2035610206 cites W2084650837 @default.
• W2035610206 cites W2092874534 @default.
• W2035610206 cites W2095446120 @default.
• W2035610206 cites W2097978803 @default.
• W2035610206 cites W2110746246 @default.
• W2035610206 cites W2120773440 @default.
• W2035610206 cites W2130410327 @default.
• W2035610206 cites W2137419733 @default.
• W2035610206 cites W2156963746 @default.
• W2035610206 cites W2160185729 @default.
• W2035610206 cites W2325954350 @default.
• W2035610206 cites W2331764702 @default.
• W2035610206 cites W3101218919 @default.
• W2035610206 cites W4211250518 @default.
• W2035610206 cites W4239950509 @default.
• W2035610206 cites W585924654 @default.
• W2035610206 doi "https://doi.org/10.1063/1.4895969" @default.
• W2035610206 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25399174" @default.
• W2035610206 hasPublicationYear "2014" @default.
• W2035610206 type Work @default.
• W2035610206 sameAs 2035610206 @default.
• W2035610206 citedByCount "15" @default.
• W2035610206 countsByYear W20356102062014 @default.
• W2035610206 countsByYear W20356102062015 @default.
• W2035610206 countsByYear W20356102062016 @default.
• W2035610206 countsByYear W20356102062017 @default.
• W2035610206 countsByYear W20356102062018 @default.
• W2035610206 countsByYear W20356102062019 @default.
• W2035610206 countsByYear W20356102062020 @default.
• W2035610206 countsByYear W20356102062022 @default.
• W2035610206 crossrefType "journal-article" @default.
• W2035610206 hasAuthorship W2035610206A5025014125 @default.
• W2035610206 hasAuthorship W2035610206A5052271356 @default.
• W2035610206 hasAuthorship W2035610206A5063060133 @default.
• W2035610206 hasAuthorship W2035610206A5063193867 @default.
• W2035610206 hasAuthorship W2035610206A5067099296 @default.
• W2035610206 hasConcept C113196181 @default.
• W2035610206 hasConcept C121332964 @default.
• W2035610206 hasConcept C145148216 @default.
• W2035610206 hasConcept C147789679 @default.
• W2035610206 hasConcept C15744967 @default.
• W2035610206 hasConcept C158622935 @default.
• W2035610206 hasConcept C159467904 @default.
• W2035610206 hasConcept C160018778 @default.
• W2035610206 hasConcept C173523689 @default.
• W2035610206 hasConcept C17525397 @default.
• W2035610206 hasConcept C178790620 @default.
• W2035610206 hasConcept C184651966 @default.

• next