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- W2035642610 abstract "Te, HgTe and Cd0.2Hg0.8Te (CMT) have been examined with the rotating-ring-disc technique. The oxidation and reduction of these materials as well as of the anodic oxides have been studied in solutions of pH 1 to 13. The soluble oxidation products of four-valent Te and two-valent Hg may be determined quantitatively at a Pt-ring. Hg metal deposits at the disc are seen by the additional formation of soluble monovalent Hg22+-ions during oxidation. Passivating oxides are formed on HgTe and CMT in weakly acidic or alkaline solutions (pH 4.9. 8.4) or in 0.1 M KOH in 90% ethylene glycol and 10% water. From the characteristics of the reduction of the anodic oxide it is deduced that a compound oxide rather than an oxide mixture is present. The HgO- and CdO-content reduce significantly the dissolution of TeO2 presumably by the formation of tellurites. At sufficiently positive potentials (E≈0 V) only the HgO-content may be reduced to Hg. At more negative values (−0.3 V) HgTe and Te are formed. The reduction of HgTe and CMT leads to Cd- and Hg-metal deposits and soluble telluride." @default.
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- W2035642610 date "1982-11-01" @default.
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- W2035642610 title "An examination of the electrode reactions of Te, HgTe and Cd0.2 Hg0.8Te with rotating-split-ring-disc electrodes" @default.
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- W2035642610 doi "https://doi.org/10.1016/0368-1874(82)85300-8" @default.
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