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- W2035674505 abstract "The infrared photodissociation spectra of Ar dimer ions have been obtained at several wavelengths with a line tunable CO2 laser. The dimer ions were produced by high energy electron impact ionization near or at the nozzle orifice of a supersonic expansion. When the electron beam is focused several millimeters from the nozzle, and the laser polarization is parallel to the dimer ion beam, the product Ar+ kinetic energy spectra exhibit structure, with a spacing of 117 cm−1. However, when the ions are produced by focusing the electron beam directly onto the nozzle, the structure largely disappears. Analysis of the results indicates that the transition is a bound to continuum transition, and that the observed spacing is associated with vibrational levels of the first excited Ar+2 I(3/2)g state." @default.
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- W2035674505 date "1994-08-15" @default.
- W2035674505 modified "2023-09-27" @default.
- W2035674505 title "Infrared vibrational photodissociation spectra of Ar+2 ions" @default.
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- W2035674505 doi "https://doi.org/10.1063/1.467594" @default.
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