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- W2035755470 abstract "Based on broadband acoustical (10 kHz < or = nu < or = 2 GHz) and dielectric (1 MHz < or = nu < or = 40 GHz) spectrometry, time-resolved ultrasonic attenuation coefficient and static permittivity measurements have been performed on nonequilibrium tautomer solutions of d-arabinose and d-fructose in water. Via the chair-chair ring inversion the ultrasonic attenuation measurements display the decrease in the content of beta-arabinopyranoside and the increase of the alpha-fructopyranoside concentration during the establishment of the tautomer equilibrium. For the arabinose solutions, the mutarotation decay constant (m=(0.027+/-0.004) min(-1), 20 degrees C) from the ultrasonic measurements almost agrees with that from optical activity observations. For d-fructose the ultrasonic decay constant (m=(0.043+/-0.007) min(-1), 20 degrees C) is smaller than that from rotary polarization (m=0.054 min(-1), 20 degrees C) and dielectric permittivity (m=(0.058+/-0.007) min(-1), 20 degrees C), likely because the latter methods probe parallel pathways in the tautomer equilibrium whereas the former one reflects only one pathway." @default.
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- W2035755470 date "2004-09-01" @default.
- W2035755470 modified "2023-09-24" @default.
- W2035755470 title "Ultrasonic and dielectric study of nonequilibrium monosaccharide solutions in water" @default.
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- W2035755470 doi "https://doi.org/10.1016/j.bpc.2004.03.011" @default.
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