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- W2035761972 abstract "Die Trifluormethylchlorsulfonierung von Alkenen gelingt durch die Kombination von sichtbarem Licht und [Cu(dap)2]Cl als Photoredoxkatalysator. Im Gegensatz dazu katalysieren [Ru(bpy)3]Cl2, [Ir(ppy)2(dtbbpy)]PF6 oder Eosin Y eine Trifluormethylchlorierung. [Cu(dap)2]Cl spielt in diesem Prozess eine zweifache Rolle: Einerseits agiert es als Elektronentransferreagens, andererseits koordiniert es die Reagentien für die Bindungsbildung." @default.
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- W2035761972 date "2015-04-29" @default.
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- W2035761972 title "Trifluormethylchlorsulfonylierung von Alkenen - Hinweise auf einen Innensphärenmechanismus eines Kupferphenanthrolin-Photoredoxkatalysators" @default.
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