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- W2035769884 abstract "Summary: Different kinds of polyethylene and ethylene-1-hexene copolymers were synthesized with TpTiCl2(OR) (Tp = hydrotris(pyrazolyl)borate; R = Et, i-Pr, n-Bu) catalysts with and without H2. The polymers were characterized by 13C NMR, capillary viscosimetry or GPC, and DSC. The homopolymers showed properties characteristic of ultra-high molecular weight polyethylenes (UHMWPE) with linear structure and high density polyethylenes (HDPE) with molecular weights in the range of commercial grades under hydrogen atmosphere. The copolymers showed a 1-hexene incorporation up to 6 mol-%. Important differences in the thermal properties were observed between the first DSC (nascent powders) and the second DSC heatings (melt-crystallized samples), which evidenced the molecular weights influence on the melt-crystallized samples." @default.
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- W2035769884 date "2007-11-01" @default.
- W2035769884 modified "2023-10-14" @default.
- W2035769884 title "Characterization of Polyethylene Nascent Powders Synthesized with TpTiCl2(OR) Catalysts" @default.
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- W2035769884 doi "https://doi.org/10.1002/masy.200751112" @default.
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