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- W2035784107 abstract "Abstract Structures of non metal-metal bonded phosphido-bridged heterobimetallic complexes, including CpFe(CO) 2 (μ-PPh 2 )W(CO) 5 ( 1 -W) and metal-metal bonded CpFe(CO)(μ-CO)(μ-PPh 2 )W(CO) 4 ( 2 ), were determined by a single crystal X-ray diffraction study. In 1 -W, the long distance between Fe and W indicates no metal-metal bond to exist. In 2 , a FeW bond with bond length 2.851 A and a semibridging carbonyl with WCO angle 153° were observed. Mossbauer spectra of 1 -W and 2 were taken at 77 K. Isomer shifts of 1 -W and 2 were − 0.0203 mm s −1 and 0. 1917 mm s −1 respectively." @default.
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- W2035784107 title "Structures and Mössbauer spectra of phosphido-bridged heterobimetallic complexes CpFe(CO)2(μ-PPh2)W(CO)5 and CpFe(CO)(μ-CO)(μ-PPh2)W(CO)4" @default.
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- W2035784107 doi "https://doi.org/10.1016/0022-328x(93)83150-t" @default.
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