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• W2035789715 abstract "Abstract The cloud‐point temperatures ( T clo 's) of poly( N ‐isopropyl acrylamide) (PNIPAM)/water solutions with NaCl, NaBr, or NaI were measured. All these salts reduced the T clo 's of PNIPAM/water solutions to different extents, in the following order: NaCl > NaBr > NaI. The higher the concentration of the added salt was, the more greatly T clo dropped. A dynamic viscoelasticity investigation of the PNIPAM/water solutions with the salts indicated that during phase separation, the system changed from a homogeneous fluid into a physically crosslinked network, and the addition of salts also reduced the temperature at which this change began. The gelation temperature ( T gel ) and the scaling exponent of the PNIPAM/water solutions with NaBr were obtained with dynamic scaling theory, and T gel was found to be close to T clo . That the addition of salts to the solution decreased T clo and T gel to the same extent further proved that the network structure was formed with the phase separation in the PNIPAM/water solutions. © 2001 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 39: 901–907, 2001" @default.
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• W2035789715 date "2001-03-09" @default.
• W2035789715 modified "2023-10-10" @default.
• W2035789715 title "Phase separation in poly(N-isopropyl acrylamide)/water solutions. II. Salt effects on cloud-point curves and gelation" @default.
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• W2035789715 doi "https://doi.org/10.1002/polb.1064" @default.
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