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• W2035797527 endingPage "1532" @default.
• W2035797527 startingPage "1528" @default.
• W2035797527 abstract "The complexes [TpBr3Ag]2·CH3COCH3 (1) and TpBr3Ag(thf) (2) catalyze the insertion of the :CHCO2Et group from ethyl diazoacetate (EDA) into the saturated C−H bonds of several C5, C6, and C8 linear and branched alkanes. In addition to secondary and/or tertiary sites, the unprecedented insertion into the primary C−H bonds of the substrates studied has been observed with variable regioselectivity, toward the methyl groups, within the range of 40−60% for branched and nearly 25% for linear alkanes." @default.
• W2035797527 created "2016-06-24" @default.
• W2035797527 creator A5028002953 @default.
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• W2035797527 date "2005-02-23" @default.
• W2035797527 modified "2023-10-17" @default.
• W2035797527 title "Functionalization of Primary Carbon−Hydrogen Bonds of Alkanes by Carbene Insertion with a Silver-Based Catalyst" @default.
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• W2035797527 doi "https://doi.org/10.1021/om050024k" @default.
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