FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2035799110> ?p ?o ?g. }

• W2035799110 endingPage "655" @default.
• W2035799110 startingPage "645" @default.
• W2035799110 abstract "A one-pot synthetic procedure yields the octanuclear FeIII complexes Fe8(μ4-O)4(μ-pz*)12X4, where X = Cl and pz* = pyrazolate anion (pz = C3H3N2-) (1), 4-Cl-pz (2), and 4-Me-pz (3) or X = Br and pz* = pz (4). The crystal structures of complexes 1−4, determined by X-ray diffraction, show an Fe4O4-cubane core encapsulated in a shell composed of four interwoven Fe(μ-pz*)3X units. Complexes 1−4 have been characterized by 1H NMR, infrared, and Raman spectroscopies. Mössbauer spectroscopic analysis distinguishes the cubane and outer FeIII centers by their different isomer shift and quadrupole splitting values. Electrochemical analyses by cyclic voltammetry show four consecutive, closely spaced, reversible reduction processes for each of the four complexes. Magnetic susceptibility studies, corroborated by density functional theory calculations, reveal weak antiferromagnetic coupling among the four cubane Fe centers and strong antiferromagnetic coupling between cubane and outer Fe atoms of 1. The structural similarity between the antiferromagnetic Fe8(μ4-O)4 core of 1−4 and the antiferromagnetic units contained in the minerals ferrihydrite and maghemite is demonstrated by X-ray and Mössbauer data." @default.
• W2035799110 created "2016-06-24" @default.
• W2035799110 creator A5005247264 @default.
• W2035799110 creator A5005648652 @default.
• W2035799110 creator A5020436129 @default.
• W2035799110 creator A5029665163 @default.
• W2035799110 creator A5035949986 @default.
• W2035799110 creator A5049759033 @default.
• W2035799110 creator A5061304204 @default.
• W2035799110 creator A5066415290 @default.
• W2035799110 creator A5076774741 @default.
• W2035799110 creator A5090938989 @default.
• W2035799110 date "2007-12-14" @default.
• W2035799110 modified "2023-10-13" @default.
• W2035799110 title "Synthesis, Characterization, and Study of Octanuclear Iron-Oxo Clusters Containing a Redox-Active Fe₄O₄-Cubane Core" @default.
• W2035799110 cites W1014502094 @default.
• W2035799110 cites W1561069392 @default.
• W2035799110 cites W1602639107 @default.
• W2035799110 cites W1692427743 @default.
• W2035799110 cites W1965284073 @default.
• W2035799110 cites W1966608102 @default.
• W2035799110 cites W1966960554 @default.
• W2035799110 cites W1968672559 @default.
• W2035799110 cites W1969293771 @default.
• W2035799110 cites W1971396352 @default.
• W2035799110 cites W1972954290 @default.
• W2035799110 cites W1976321043 @default.
• W2035799110 cites W1981704948 @default.
• W2035799110 cites W1984758431 @default.
• W2035799110 cites W1988785503 @default.
• W2035799110 cites W1994399338 @default.
• W2035799110 cites W1998963261 @default.
• W2035799110 cites W2000619473 @default.
• W2035799110 cites W2002564429 @default.
• W2035799110 cites W2003873180 @default.
• W2035799110 cites W2005438107 @default.
• W2035799110 cites W2006927358 @default.
• W2035799110 cites W2012313382 @default.
• W2035799110 cites W2014126369 @default.
• W2035799110 cites W2021010920 @default.
• W2035799110 cites W2023271753 @default.
• W2035799110 cites W2023952564 @default.
• W2035799110 cites W2024260356 @default.
• W2035799110 cites W2025108578 @default.
• W2035799110 cites W2031038613 @default.
• W2035799110 cites W2034063871 @default.
• W2035799110 cites W2035665578 @default.
• W2035799110 cites W2043738901 @default.
• W2035799110 cites W2044490585 @default.
• W2035799110 cites W2049150201 @default.
• W2035799110 cites W2049381544 @default.
• W2035799110 cites W2050581004 @default.
• W2035799110 cites W2051509289 @default.
• W2035799110 cites W2052642314 @default.
• W2035799110 cites W2052846606 @default.
• W2035799110 cites W2053923792 @default.
• W2035799110 cites W2055844532 @default.
• W2035799110 cites W2062478772 @default.
• W2035799110 cites W2062485571 @default.
• W2035799110 cites W2062837393 @default.
• W2035799110 cites W2065140185 @default.
• W2035799110 cites W2066920637 @default.
• W2035799110 cites W2068617439 @default.
• W2035799110 cites W2078860799 @default.
• W2035799110 cites W2080902624 @default.
• W2035799110 cites W2082214934 @default.
• W2035799110 cites W2090079874 @default.
• W2035799110 cites W2090829112 @default.
• W2035799110 cites W2091043643 @default.
• W2035799110 cites W2093854681 @default.
• W2035799110 cites W209433882 @default.
• W2035799110 cites W2102849177 @default.
• W2035799110 cites W2104594638 @default.
• W2035799110 cites W2104796556 @default.
• W2035799110 cites W2106873948 @default.
• W2035799110 cites W2107228249 @default.
• W2035799110 cites W2112876394 @default.
• W2035799110 cites W2116070823 @default.
• W2035799110 cites W2119055016 @default.
• W2035799110 cites W2136078186 @default.
• W2035799110 cites W2143981217 @default.
• W2035799110 cites W2156605690 @default.
• W2035799110 cites W2162893449 @default.
• W2035799110 cites W2165966788 @default.
• W2035799110 cites W2167590372 @default.
• W2035799110 cites W2170087828 @default.
• W2035799110 cites W2300203077 @default.
• W2035799110 cites W2939298525 @default.
• W2035799110 cites W2952532516 @default.
• W2035799110 cites W4230597968 @default.
• W2035799110 cites W4231960227 @default.
• W2035799110 doi "https://doi.org/10.1021/ic7020337" @default.
• W2035799110 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/2535771" @default.
• W2035799110 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18078337" @default.
• W2035799110 hasPublicationYear "2007" @default.
• W2035799110 type Work @default.
• W2035799110 sameAs 2035799110 @default.
• W2035799110 citedByCount "56" @default.

• next