FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2035808109> ?p ?o ?g. }

• W2035808109 endingPage "1816" @default.
• W2035808109 startingPage "1807" @default.
• W2035808109 abstract "The effects of structural constraint on the thermosensitivity and dynamic self-assembly behaviors of PNIPAM-based nonlinear multihydrophilic block copolymers (MHBCs) are investigated by a combination of calorimetric, NMR, FTIR, DLS and zeta potential measurements. Two novel miktoarm star MHBCs, (PNIPAM)2-(PVP-b-PAA)2 with PNIPAM segments constrained at one end and (PNIPAM-b-PAA)2-(PVP)2 with PNIPAM segments constrained at two ends, are mainly analyzed to make comparison. As we previously reported (Soft Matter, 2012, 8, 3980), in (PNIPAM)2-(PVP-b-PAA)2 the three polymeric segments have relatively independent phase behaviors during the formation of PNIPAM-core micelles. However, by introducing more structural constraints to PNIPAM segments, (PNIPAM-b-PAA)2-(PVP)2 exhibits a much smoother and weaker phase transition. Additional analysis by IR spectroscopy, in combination with perturbation correlation moving window (PCMW) and two-dimensional correlation spectroscopy (2DCOS), indicates that PVP segments in (PNIPAM-b-PAA)2-(PVP)2 show phase transition-like behavior by participating in the self-association process of PNIPAM segments, and there are both unimers and small associates existing in the solution below the LCST due to the slight interaction between PVP and PNIPAM segments. Moreover, due to the presence of PVP segments in the core, the micelles formed by (PNIPAM-b-PAA)2-(PVP)2 should have a loosely organized superstructure, which may account for the weak phase transition and low degree of phase separation. Finally, we propose a mechanism of the self-assembly process of (PNIPAM-b-PAA)2-(PVP)2, which is further confirmed by DLS and zeta potential measurements." @default.
• W2035808109 created "2016-06-24" @default.
• W2035808109 creator A5013617244 @default.
• W2035808109 creator A5025978277 @default.
• W2035808109 creator A5027324209 @default.
• W2035808109 creator A5068428294 @default.
• W2035808109 creator A5076699095 @default.
• W2035808109 date "2013-01-01" @default.
• W2035808109 modified "2023-09-28" @default.
• W2035808109 title "Effect of structural constraint on dynamic self-assembly behavior of PNIPAM-based nonlinear multihydrophilic block copolymers" @default.
• W2035808109 cites W1966333498 @default.
• W2035808109 cites W1981497065 @default.
• W2035808109 cites W1984343856 @default.
• W2035808109 cites W1985031184 @default.
• W2035808109 cites W1985644707 @default.
• W2035808109 cites W1987617728 @default.
• W2035808109 cites W1993505062 @default.
• W2035808109 cites W1996292197 @default.
• W2035808109 cites W1997828866 @default.
• W2035808109 cites W2006377871 @default.
• W2035808109 cites W2008780929 @default.
• W2035808109 cites W2015125674 @default.
• W2035808109 cites W2015491525 @default.
• W2035808109 cites W2019006094 @default.
• W2035808109 cites W2019429598 @default.
• W2035808109 cites W2020325566 @default.
• W2035808109 cites W2021775213 @default.
• W2035808109 cites W2023192003 @default.
• W2035808109 cites W2026340057 @default.
• W2035808109 cites W2035693898 @default.
• W2035808109 cites W2044979664 @default.
• W2035808109 cites W2045864632 @default.
• W2035808109 cites W2048999914 @default.
• W2035808109 cites W2052641548 @default.
• W2035808109 cites W2054597481 @default.
• W2035808109 cites W2059662220 @default.
• W2035808109 cites W2067615265 @default.
• W2035808109 cites W2068426524 @default.
• W2035808109 cites W2070939019 @default.
• W2035808109 cites W2074612617 @default.
• W2035808109 cites W2075493870 @default.
• W2035808109 cites W2079042829 @default.
• W2035808109 cites W2083663654 @default.
• W2035808109 cites W2085336382 @default.
• W2035808109 cites W2089036678 @default.
• W2035808109 cites W2092700187 @default.
• W2035808109 cites W2093195378 @default.
• W2035808109 cites W2095489167 @default.
• W2035808109 cites W2110485013 @default.
• W2035808109 cites W2110950744 @default.
• W2035808109 cites W2111162778 @default.
• W2035808109 cites W2111812628 @default.
• W2035808109 cites W2116431346 @default.
• W2035808109 cites W2122821125 @default.
• W2035808109 cites W2132075000 @default.
• W2035808109 cites W2132956066 @default.
• W2035808109 cites W2145037410 @default.
• W2035808109 cites W2147788278 @default.
• W2035808109 cites W2168063840 @default.
• W2035808109 cites W2171118412 @default.
• W2035808109 cites W2331598181 @default.
• W2035808109 cites W2332656300 @default.
• W2035808109 cites W2490526535 @default.
• W2035808109 doi "https://doi.org/10.1039/c2sm27183d" @default.
• W2035808109 hasPublicationYear "2013" @default.
• W2035808109 type Work @default.
• W2035808109 sameAs 2035808109 @default.
• W2035808109 citedByCount "40" @default.
• W2035808109 countsByYear W20358081092012 @default.
• W2035808109 countsByYear W20358081092013 @default.
• W2035808109 countsByYear W20358081092014 @default.
• W2035808109 countsByYear W20358081092015 @default.
• W2035808109 countsByYear W20358081092016 @default.
• W2035808109 countsByYear W20358081092017 @default.
• W2035808109 countsByYear W20358081092018 @default.
• W2035808109 countsByYear W20358081092019 @default.
• W2035808109 countsByYear W20358081092020 @default.
• W2035808109 countsByYear W20358081092021 @default.
• W2035808109 countsByYear W20358081092022 @default.
• W2035808109 countsByYear W20358081092023 @default.
• W2035808109 crossrefType "journal-article" @default.
• W2035808109 hasAuthorship W2035808109A5013617244 @default.
• W2035808109 hasAuthorship W2035808109A5025978277 @default.
• W2035808109 hasAuthorship W2035808109A5027324209 @default.
• W2035808109 hasAuthorship W2035808109A5068428294 @default.
• W2035808109 hasAuthorship W2035808109A5076699095 @default.
• W2035808109 hasConcept C11268172 @default.
• W2035808109 hasConcept C127413603 @default.
• W2035808109 hasConcept C14631669 @default.
• W2035808109 hasConcept C147789679 @default.
• W2035808109 hasConcept C155672457 @default.
• W2035808109 hasConcept C15920480 @default.
• W2035808109 hasConcept C159985019 @default.
• W2035808109 hasConcept C171250308 @default.
• W2035808109 hasConcept C178790620 @default.
• W2035808109 hasConcept C184651966 @default.
• W2035808109 hasConcept C185592680 @default.
• W2035808109 hasConcept C188027245 @default.

• next