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• W2035808198 endingPage "6939" @default.
• W2035808198 startingPage "6939" @default.
• W2035808198 abstract "The reactions of bis(mercaptoimidazolyl)hydroborato derivatives [BmR]M′ (R = Me, But; M′ = Li, Na, Tl) with MX3 trihalides of aluminium, gallium and indium yield both 1 : 1 and 2 : 1 complexes of the types [BmR]MX2 and [BmR]2MX, respectively. Structurally characterized examples of the [BmR]MX2 series include [BmMe]AlCl2, [BmMe]GaI2, [BmMe]InI2, [BmBut]AlCl2 and [BmBut]GaX2 (X = Cl, Br, I), while structurally characterized examples of the [BmR]2MX series include [BmBut]2InX (X = Cl, Br, I). In addition to the halide complexes, the trivalent dimethyl thallium complex [BmBut]TlMe2 has been synthesized via the reaction of [BmBut]Tl with Me2TlCl. The reactions of [BmR]M′ with the monovalent halides, “GaI”, InCl and InI, result in disproportionation. In the case of indium, the mononuclear complexes [BmBut]2InI and [BmBut]InCl(κ2-mimBut) are obtained, whereas for gallium, dinuclear compounds that feature Ga–Ga bonds, namely [BmR](GaI)(GaI)[BmR] (R = Me, But) have been isolated." @default.
• W2035808198 created "2016-06-24" @default.
• W2035808198 creator A5017379733 @default.
• W2035808198 creator A5043638933 @default.
• W2035808198 creator A5072093741 @default.
• W2035808198 date "2010-01-01" @default.
• W2035808198 modified "2023-10-18" @default.
• W2035808198 title "Bis(2-mercapto-1-R-imidazolyl)hydroborato complexes of aluminium, gallium, indium and thallium: compounds possessing gallium–gallium bonds and a trivalent thallium alkyl" @default.
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• W2035808198 doi "https://doi.org/10.1039/c0dt00461h" @default.
• W2035808198 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20596580" @default.
• W2035808198 hasPublicationYear "2010" @default.
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