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- W2035808218 abstract "The proton coupling constants of six α-hydroxylated, two β-hydroxylated, and three α,β-hydroxylated anthrasemiquinones were measured by EPR and the constants assigned by application of equations derived from additivity principles. For hydroxylations at α positions the perturbations of the spin densities are confined mainly to the benzene ring containing the substituent whereas for hydroxylations at β positions large perturbations are observed in the other benzene ring as well. Negative spin densities are predicted at certain positions of some β-hydroxylated structures. For six compounds hydroxyl proton splittings are observed and distinguished by deuterium experiments, and an unequivocal assignment is obtained." @default.
- W2035808218 created "2016-06-24" @default.
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- W2035808218 date "1981-06-01" @default.
- W2035808218 modified "2023-10-16" @default.
- W2035808218 title "EPR study of hydroxyanthrasemiquinones. Assignment of hyperfine structure by additivity" @default.
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- W2035808218 doi "https://doi.org/10.1016/0022-2364(81)90049-4" @default.
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