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- W2035863380 abstract "Reaction of dichloro(2,2,N,N-tetramethyl-3-buten-1-amine)palladium(II) with diazomethane in ether/ethanol leads to the carbene insertion product, a-chloro-b-(chloromethyl)-d,c-(2,2,N,N-tetramethyl-3-buten-1-amine)palladium(II) and the analogous ethoxymethyl and methyl complexes. Similar treatment of dichloro(2,2-dimethyl-3-buten-1-yl methyl sulfide)palladium(II) gives the chloromethyl complex and a product of cyclopropanation." @default.
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- W2035863380 date "1985-03-01" @default.
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- W2035863380 title "Reaction of diazomethane with the palladium(II) chloride complexes of 2,2,N,N-tetramethyl-3-buten-1-amine and 2,2-dimethyl-3-buten-1-yl methyl sulfide. Carbene insertion" @default.
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- W2035863380 doi "https://doi.org/10.1016/0022-328x(85)87199-0" @default.
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