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- W2035910879 abstract "For a comprehensive description of the steric structure of macromolecules, which includes molecular shape as well as coil density and flexibility, a novel analytical technique for aqueous systems is introduced. The reliability of the method is illustrated by investigations on narrowly distributed pullulan standards in the molar mass range from 105 to 106 g mol−1. Hydrodynamic information (D, RD) was yielded by flow field-flow fractionation, while simultaneous scattering experiments delivered the corresponding ‘static’ dimension RG and molar mass M. The observed asymmetry-factor was RGRD = 1.7. With increasing molar mass the mean coil density ρPol decreased from 19.1 to 2.6 mg ml−1 and the calculated persistence lengths lP increased, ranging from 1.4 to 3.1 nm. The results were found to be in good agreement with literature data and confirm the analytical potential of the applied technique." @default.
- W2035910879 created "2016-06-24" @default.
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- W2035910879 date "1997-03-01" @default.
- W2035910879 modified "2023-09-27" @default.
- W2035910879 title "Coil dimensions and conformation of macromolecules in aqueous media from flow field-flow fractionation/multi-angle laser light scattering illustrated by studies on pullulan" @default.
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- W2035910879 doi "https://doi.org/10.1016/s0032-3861(96)00675-1" @default.
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