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- W2035935136 abstract "Measurements have been made on the vibration—vibration (V—V) energy exchange rate between carbon monoxide and carbon dioxide in the temperature range 180 to 345 K. A steady-state vibrational fluorecence quenching technique was used in conjunction with an open flow gas system. Vibrational excitation of the carbon monoxide was accomplished by absorption of infrared radiation from prospane—oxygen flames. The measured rate constant for the process CO* (υ = 1) + CO2 → CO + CO*2(001) increased linearly with temperature, and after correction for the V—V exchange rate fo the back reaction, the rate constant has a value of (2.2 ± 0.3) × 103 torr−1 s−1 at 296 K. The data are compared to results at highest temperatures and to available theoretical calculations." @default.
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- W2035935136 date "1974-11-01" @default.
- W2035935136 modified "2023-09-24" @default.
- W2035935136 title "Vibration—vibration energy exchange between carbon monoxide and carbon dioxide" @default.
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- W2035935136 doi "https://doi.org/10.1016/0301-0104(74)85072-x" @default.
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