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- W2035993566 abstract "Die Natriumsalze von Acetessigester und Benzoylessigester liefern in alkoholischer Lösung mit den 1-Acylaziridinen 1a–d die 3-Acetyl-1-acyl-2-pyrrolidone 5a–d bzw. die Benzoyl-1-acyl-2-pyrrolidone 5e–g, die alle deutlich enolisieren. Von 5e wurde sowohl die Keto- als auch die Enolform kristallin erhalten. Reactions with Aziridines, XIV. Synthesis and Keto Enol Tautomerism of 1,3-Diacyl-2-pyrrolidones Reactions of the sodium salts of acetoacetic esters and of ethyl benzoylacetate with the 1-acylaziridines 1a–d in alcoholic solution yield the 3-acetyl-1-acyl-2-pyrrolidones 5a–d and the 3-benzoyl-1-acyl-2-pyrrolidones 5e–g, respectively. All of these products enolise markedly. 5e could be crystallised as the ketone and as the enol." @default.
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- W2035993566 date "1977-01-01" @default.
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- W2035993566 title "Reaktionen mit Aziridinen, XIV. Synthese und Keto-Enol-Tautomerie von 1,3-Diacyl-2-pyrrolidonen" @default.
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- W2035993566 doi "https://doi.org/10.1002/ardp.19773100407" @default.
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