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- W2035996824 abstract "Abstract The reactions of the two isomeric series (α and β) of complex hydrides of rhodium of the type RhH X 2 L 3 ( X is a halogen and L is a tertiary arsine or phosphine) with the nitrogen donor ligands 2,2′-dipyridyl ( N - N ) and 1,10-phenanthroline ( N - N ) have been investigated. In presence of perchloric acid the α hydrides give new hydrido compounds of the type [RhH X ( N - N ) L 2 ]ClO 4 , while the β hydrides give complexes of the type [Rh X 2 ( N - N ) L 2 ]ClO 4 . Under similar conditions trihalo compounds of rhodium of the type Rh X 3 L 3 also give compounds similar to those obtained from the corresponding β hydrides. Configurations for the cationic species have been assigned on the basis of results of i.r. and NMR measurements." @default.
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- W2035996824 date "1974-12-01" @default.
- W2035996824 modified "2023-09-27" @default.
- W2035996824 title "Hydride and related complexes of rhodium(III) with nitrogen donor ligands" @default.
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- W2035996824 doi "https://doi.org/10.1016/0022-1902(74)80159-4" @default.
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