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- W2036008214 abstract "Abstract The thermal evolution of the crystal structure of PrSr 3 Co 1.5 Fe 1.5 O 10– d , a member of the n = 3 family of Ruddlesden-Popper compounds, has been studied by means of variable temperature synchrotron X-ray powder diffraction combined with room temperature neutron diffraction studies. This structure takes the ideal tetragonal I 4/ mmm ( n °139) space group. The possibility of symmetry lowering to the Pbca ( n °61) space group by slight tilting and rotation of the oxygen atoms around the octahedral B site is discussed. The non linear thermal expansion of the compound in air is caused by a chemical expansion accompanying the loss of oxygen that comes in addition to normal thermal expansion. A mechanism describing the creation of oxygen vacancies is proposed." @default.
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- W2036008214 date "2009-05-01" @default.
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- W2036008214 title "Temperature dependant X-ray diffraction study of PrSr3Co1.5Fe1.5O10–d ; n = 3 Ruddlesden-Popper phase" @default.
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- W2036008214 doi "https://doi.org/10.1524/zkri.2009.1156" @default.
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