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- W2036017164 abstract "Synchrotron X-ray diffraction (XRD) during the atmospheric oxidation of epitaxial Nb(1 1 0) films at elevated temperature reveals the formation of highly ordered oxygen phases within the Nb lattice. The oxygen is stored on interstitial lattice sites without destroying the basic BCC structure of the Nb host lattice. However the lattice exhibits an out-of-plane lattice expansion of up to 4.3%. During oxidation we observe the formation of a non-ordered lattice gas phase succeeded by a well-defined sequence of oxygen superstructures until finally the whole film is consumed by the formation of amorphous Nb2O5. We show that XRD is an excellent tool to monitor the exact evolution of the different oxygen phases. In addition we demonstrate that UHV post-annealing of partially oxidized films can be used to rearrange the oxygen within the sample while keeping the overall amount of oxygen constant." @default.
- W2036017164 created "2016-06-24" @default.
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- W2036017164 date "2003-08-01" @default.
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- W2036017164 title "Oxygen ordering in Nb(110) films" @default.
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- W2036017164 doi "https://doi.org/10.1016/s0921-4526(03)00274-6" @default.
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