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- W2036020753 abstract "Abstract The new complexes [Os 111 Cl 2 (PPh 3 ) 2 SQ′] (SQ′ = o -semiquinone; 1,2-benzosemiquinone (SQ), 4-methyl-1,2-benzosemiquinone, 3,5-di(tert-butyl)-l,2-benzosemiquinone, tetrachloro(tetrabromo)-l,2-benzosemiquinone and 2,3-naphthosemiquinone) have been isolated. They were characterised by spectroscopic techniques and investigated by cyclic voltammetry. The complex [OsCl 2 (PPh 3 ) 2 SQ] was found to be more efficient than the reported [Os 111 Cl 2 (PPh 3 ) 2 acac] as a catalyst for the oxidation of primary alcohols to aldehydes and of secondary alcohols to ketones in the presence of N -methylmorpholine- N -oxide as co-oxidant." @default.
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- W2036020753 date "1991-01-01" @default.
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- W2036020753 title "Osmium(III)o-semiquinonato complexes and their use as catalysts for the oxidation of alcohols" @default.
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- W2036020753 doi "https://doi.org/10.1016/s0020-1693(00)85881-8" @default.
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