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- W2036022018 abstract "N-Carbamoyl-α-hydroxy oxazolidines prepared from N-Boc-2-acyl oxazolidines or N-Boc-2-alkenyl oxazolidines, using phenyl glycinol as the chiral source, are converted into bicyclic oxazolidinones. Reactions of these compounds with different nucleophiles under conditions suitable for the production of N-acyliminium ions were studied. Allylsilane reacted very stereoselectively in all cases, and this reaction provides a new flexible entry for the preparation of enantiopure syn-2-amino alcohols, possibly bearing an additional stereocenter α to the hydroxyl moiety." @default.
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- W2036022018 date "1998-11-01" @default.
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- W2036022018 title "Chiral oxazolidinones from α-hydroxy oxazolidines: a new access to 1,2-amino alcohols" @default.
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- W2036022018 doi "https://doi.org/10.1016/s0957-4166(98)00414-5" @default.
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