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- W2036034095 abstract "Abstract The air-, and thermo-stable palladium(II) complexes C1–C10 are prepared by the reaction of PdCl2(CH3CN)2 with pyridylbenzoimidazole. With various substituents on the pyridine ring, palladium atom was coordinated by two pyridylbenzoimidazole molecules via nitrogen atoms of benzoimidazole. The structure of complexes C3, C4, C6, and C7 has been confirmed by X-ray diffraction analysis. Without substituents on the pyridine ring, palladium atom was directly coordinated with two nitrogen atoms of pyridine and benzoimidazole nitrogen via intramolecular chelation (C10). These complexes performed the Heck olefination of aryl bromides in a good to high yield under phosphine-free conditions." @default.
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- W2036034095 date "2008-01-22" @default.
- W2036034095 modified "2023-09-27" @default.
- W2036034095 title "ChemInform Abstract: Highly Active Pd(II) Catalysts with Pyridylbenzoimidazole Ligands for the Heck Reaction." @default.
- W2036034095 cites W2953119938 @default.
- W2036034095 doi "https://doi.org/10.1002/chin.200804091" @default.
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