FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2036036769> ?p ?o ?g. }

• W2036036769 endingPage "6907" @default.
• W2036036769 startingPage "6902" @default.
• W2036036769 abstract "A combined computational and experimental investigation provides evidence that excited thorium and uranium atoms activate ethane to form the vinyl metal trihydride, metallacyclopropane dihydride, and ethylidene metal dihydride for thorium and the latter complex and the inserted ethyl metal hydride for uranium. These products are trapped in solid argon and identified through deuterium isotopic substitution and vibrational frequencies calculated by densitiy functional theory. Comparisons are made with group 4 and methane reaction products. Numerous calculations using several methods show that these simple ethylidene complexes are more distorted by the agostic interaction than the corresponding methylidene species. This enhanced agostic interaction probably arises from methyl hydrogen to α-H repulsions, which leads to a substantial decrease in the α-H to Th agostic interaction distance, and contributes to our understanding of agostic distortion in organometallic complexes." @default.
• W2036036769 created "2016-06-24" @default.
• W2036036769 creator A5012036593 @default.
• W2036036769 creator A5029634322 @default.
• W2036036769 creator A5036641250 @default.
• W2036036769 date "2008-07-01" @default.
• W2036036769 modified "2023-09-27" @default.
• W2036036769 title "Reactions of Actinide Metal Atoms with Ethane: Computation and Observation of New Th and U Ethylidene Dihydride, Metallacyclopropane Dihydride, and Vinyl Metal Trihydride Complexes" @default.
• W2036036769 cites W1963708376 @default.
• W2036036769 cites W1965336571 @default.
• W2036036769 cites W1971955616 @default.
• W2036036769 cites W1983058267 @default.
• W2036036769 cites W1996951769 @default.
• W2036036769 cites W1999128463 @default.
• W2036036769 cites W2013098681 @default.
• W2036036769 cites W2014359892 @default.
• W2036036769 cites W2023271753 @default.
• W2036036769 cites W2030340979 @default.
• W2036036769 cites W2047192738 @default.
• W2036036769 cites W2049996223 @default.
• W2036036769 cites W2061429138 @default.
• W2036036769 cites W2061717482 @default.
• W2036036769 cites W2062925914 @default.
• W2036036769 cites W2078612723 @default.
• W2036036769 cites W2086288648 @default.
• W2036036769 cites W2087050385 @default.
• W2036036769 cites W2089039541 @default.
• W2036036769 cites W2126777191 @default.
• W2036036769 cites W2143532958 @default.
• W2036036769 cites W2143981217 @default.
• W2036036769 cites W2154270367 @default.
• W2036036769 cites W2164225681 @default.
• W2036036769 cites W2168582519 @default.
• W2036036769 cites W2328071225 @default.
• W2036036769 cites W2409006251 @default.
• W2036036769 cites W2949249906 @default.
• W2036036769 cites W2950087481 @default.
• W2036036769 cites W2951295680 @default.
• W2036036769 cites W2952253238 @default.
• W2036036769 doi "https://doi.org/10.1021/jp801692s" @default.
• W2036036769 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18610992" @default.
• W2036036769 hasPublicationYear "2008" @default.
• W2036036769 type Work @default.
• W2036036769 sameAs 2036036769 @default.
• W2036036769 citedByCount "37" @default.
• W2036036769 countsByYear W20360367692012 @default.
• W2036036769 countsByYear W20360367692013 @default.
• W2036036769 countsByYear W20360367692014 @default.
• W2036036769 countsByYear W20360367692016 @default.
• W2036036769 countsByYear W20360367692017 @default.
• W2036036769 countsByYear W20360367692018 @default.
• W2036036769 countsByYear W20360367692019 @default.
• W2036036769 countsByYear W20360367692021 @default.
• W2036036769 countsByYear W20360367692022 @default.
• W2036036769 countsByYear W20360367692023 @default.
• W2036036769 crossrefType "journal-article" @default.
• W2036036769 hasAuthorship W2036036769A5012036593 @default.
• W2036036769 hasAuthorship W2036036769A5029634322 @default.
• W2036036769 hasAuthorship W2036036769A5036641250 @default.
• W2036036769 hasConcept C121332964 @default.
• W2036036769 hasConcept C135788738 @default.
• W2036036769 hasConcept C147597530 @default.
• W2036036769 hasConcept C147789679 @default.
• W2036036769 hasConcept C152365726 @default.
• W2036036769 hasConcept C178790620 @default.
• W2036036769 hasConcept C179104552 @default.
• W2036036769 hasConcept C184779094 @default.
• W2036036769 hasConcept C185592680 @default.
• W2036036769 hasConcept C188328357 @default.
• W2036036769 hasConcept C191897082 @default.
• W2036036769 hasConcept C192562407 @default.
• W2036036769 hasConcept C2777961443 @default.
• W2036036769 hasConcept C512968161 @default.
• W2036036769 hasConcept C527038400 @default.
• W2036036769 hasConcept C544153396 @default.
• W2036036769 hasConcept C555451288 @default.
• W2036036769 hasConcept C58364064 @default.
• W2036036769 hasConceptScore W2036036769C121332964 @default.
• W2036036769 hasConceptScore W2036036769C135788738 @default.
• W2036036769 hasConceptScore W2036036769C147597530 @default.
• W2036036769 hasConceptScore W2036036769C147789679 @default.
• W2036036769 hasConceptScore W2036036769C152365726 @default.
• W2036036769 hasConceptScore W2036036769C178790620 @default.
• W2036036769 hasConceptScore W2036036769C179104552 @default.
• W2036036769 hasConceptScore W2036036769C184779094 @default.
• W2036036769 hasConceptScore W2036036769C185592680 @default.
• W2036036769 hasConceptScore W2036036769C188328357 @default.
• W2036036769 hasConceptScore W2036036769C191897082 @default.
• W2036036769 hasConceptScore W2036036769C192562407 @default.
• W2036036769 hasConceptScore W2036036769C2777961443 @default.
• W2036036769 hasConceptScore W2036036769C512968161 @default.
• W2036036769 hasConceptScore W2036036769C527038400 @default.
• W2036036769 hasConceptScore W2036036769C544153396 @default.
• W2036036769 hasConceptScore W2036036769C555451288 @default.
• W2036036769 hasConceptScore W2036036769C58364064 @default.
• W2036036769 hasIssue "30" @default.
• W2036036769 hasLocation W20360367691 @default.
• W2036036769 hasLocation W20360367692 @default.

• next