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- W2036039801 abstract "Methyl oct-cis-2-enoate was synthesized by selective hydrogenation of methyl oct-2-ynoate at atmospheric pressure with quinoline poisoned palladium as catalyst. The resulting product contained only 7% of thetrans form, as determined by GLC. The structure was confirmed by infrared spectra. Analysis of the infrared spectra is given. The cis andtrans forms of methyl oct-2-enoate were separable by GLC in polar or non-polar columns. GLC runs in polar and non-polar phases showed that the ॅ position of the double bond of methyl oct-2-enoate so affects its properties, that practically no interaction was observed between the double bond and the polar phase. Consequently volatility was the main factor determining the retention times of cis andtrans methyl oct-2-enoate in the polar and non-polar phases studied." @default.
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- W2036039801 date "1964-02-01" @default.
- W2036039801 modified "2023-09-23" @default.
- W2036039801 title "Methyl Oct-cis-2-enoate. its synthesis, GLC behaviour and infrared spectra" @default.
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- W2036039801 doi "https://doi.org/10.1007/bf02673479" @default.
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