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• W2036083618 abstract "The cubic-plus-association (CPA) equation of state has been previously applied to vapor−liquid, liquid−liquid, and solid−liquid equilibria of mixtures containing associating compounds (water, alcohols, glycols, acids, amines). Although some high-pressure applications have been presented, emphasis was given to low pressures and liquid−liquid equilibria. In this work, CPA is applied to two classes of mixtures containing polar chemicals for which high-pressure data are available:  acetone-containing systems and dimethyl ether mixtures. They are of both scientific and industrial importance. Moreover, CPA is applied to high-pressure solid−liquid equilibria (SLE) for alcohol−alkane mixtures. In the case of acetone−hydrocarbon mixtures, satisfactory results are achieved if acetone is allowed to self-associate. Satisfactory high-pressure acetone−water vapor−liquid equilibrium (VLE) is obtained, comparable to conventional models such as MHV2. Very good results are also obtained for multicomponent vapor−liquid−liqu..." @default.
• W2036083618 created "2016-06-24" @default.
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• W2036083618 date "2006-01-17" @default.
• W2036083618 modified "2023-09-25" @default.
• W2036083618 title "Application of the Cubic-Plus-Association Equation of State to Mixtures with Polar Chemicals and High Pressures" @default.
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• W2036083618 doi "https://doi.org/10.1021/ie0509241" @default.
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