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- W2036084927 abstract "Abstract Thin films produced by laser breakdown chemical vapor deposition from nickel and iron carbonyls and by implanting Ni foils with varying levels of C have been characterizea by transmission electron microscopy. Decomposition of Ni(CO) 4 produces polycrystalline films of fcc Ni and metastable ordered nexaogonal Ni 3 C. This metastable phase is identical to that produced by gas carburization, rapid solidification of Ni-C melts, and ion implantation ot C into Ni at low;co ncentrations. Increasing the H 2 content in the gas mixture during laser deposition reduces the grain size of the films significantly witn grain sizes smaller than 10 nanometers produced. Laser uecomposition of Fe(CO) 5 produces films with islands of fcc gamma-Fe and finely dispersed metastable Fe 3 C (Cementite). In addition, the ferrous oxides Fe 2 O 3 and Fe 3 O 4 were found in these samples. Implants of C into pure Ni foils at 77°K and at a concentration of 35 at.% produced amorphous layers. Implants at the same dose at room temperature did not proouce amorphous layers." @default.
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- W2036084927 date "1986-01-01" @default.
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- W2036084927 title "Microstructure of Metastable Metallic Alloy Films Produced by Laser Breakdown Chemical Vapor Deposition and Ion Implantation" @default.
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- W2036084927 doi "https://doi.org/10.1557/proc-80-269" @default.
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