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• W2036090075 abstract "Abstract A variety of problems in the growth of wide band gap II/VI materials by MOVPE has been addressed by the use of alternative precursors. The quality of grown layers of ZnSe has been greatly improved by adduct purification of Me 2 Zn. Using 4,4′‐bipyridyl, the recovery of Me 2 Zn is variable because of the insolubility of 4,4′‐bipyridyl in diethylether. Higher yields can be obtained using the ether‐soluble base 1,3‐bis(4‐pyridyl)propane. t BuSH has been introduced for the growth of ZnS. Being a liquid, this compound is easy to handle and it allows growth of high‐quality ZnS at temperatures down to 325°C with very little gas phase pre‐reaction with Me 2 Zn. Growth of ZnS x Se 1 − x at atmospheric pressure using H 2 S and Et 2 Se as the group 16 precursors allows excellent stoichiometric control, since the ratio of S : Se in the grown solid is similar to that of H 2 S : Et 2 Se in the gas phase for all compositions. Finally, multilayer structures have been grown at low pressure with excellent interface abruptness and goodquality material. However, the ternary layers are all much higher in sulphur than expected from the gas phase composition and the composition of the ternary appears to be influenced by the nature of the surface on which it is growing." @default.
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• W2036090075 date "1994-01-01" @default.
• W2036090075 modified "2023-09-27" @default.
• W2036090075 title "Tackling problems in the growth of ZnS/Se through precursor design" @default.
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• W2036090075 doi "https://doi.org/10.1002/amo.860030123" @default.
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