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• W2036092466 startingPage "9" @default.
• W2036092466 abstract "In the reactive systems F + CH3OH, F + CH3OD, F + CD3OD the emission spectra were recorded from HF and/or DF in the fundamental region. Fluorine atom attack occurs at the methyl and at the hydroxyl end of the alcohols. Vibrational relaxation was suppressed and rotational relaxation took place only to a minor extent. The relative populations NυJ, which are therefore proportional to relative detailed rate constants, were used to evaluate internal branching ratios and kinetic isotope effects. For the attack of the methyl group kH/kD = 1.2 ± 0.3 and for the attack of the hydroxyl group kH/kD = 0.6 ± 0.2 were deduced. It is concluded that HF(DF) excitation takes place up to the thermodynamical limit in all cases. <fV > ranges between 0.41 and 0.53, <fR> between 0.02 and 0.06." @default.
• W2036092466 created "2016-06-24" @default.
• W2036092466 creator A5028671803 @default.
• W2036092466 creator A5071490970 @default.
• W2036092466 date "1980-12-01" @default.
• W2036092466 modified "2023-09-26" @default.
• W2036092466 title "Infrared chemiluminescent reactions of fluorine atoms with methanol and some deuterated analogs" @default.
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• W2036092466 doi "https://doi.org/10.1016/0301-0104(80)80030-9" @default.
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