Matches in SemOpenAlex for { <https://semopenalex.org/work/W2036093500> ?p ?o ?g. }
- W2036093500 endingPage "7857" @default.
- W2036093500 startingPage "7847" @default.
- W2036093500 abstract "A new class of C2-symmetric chiral bidentate phosphonite ligands has been synthesized in moderate to good yields from readily available starting materials. Application of these air-stable chiral phosphonites in the RhI-catalyzed asymmetric hydroformylation of styrene derivatives, vinyl acetate, and allyl cyanide afforded the corresponding chiral aldehydes with high regio- and enantioselectivities under mild reaction conditions. The modular nature of the ligands allows fine-tuning of the selectivities through judicious modifications of the substituents on the ligand backbone. X-ray structural analysis of the catalyst precursor suggested that the steric hindrance caused by the protruding remote substituents of the ligands into the vicinity of the metal center might be an important factor for the enantio-control of the reaction, whereas the sense of asymmetric induction can be rationalized on the basis of a trigonal-bipyramidal transition state diagram." @default.
- W2036093500 created "2016-06-24" @default.
- W2036093500 creator A5016648658 @default.
- W2036093500 creator A5017639833 @default.
- W2036093500 creator A5052267876 @default.
- W2036093500 creator A5057500089 @default.
- W2036093500 creator A5063835443 @default.
- W2036093500 date "2008-09-08" @default.
- W2036093500 modified "2023-09-23" @default.
- W2036093500 title "Modular Chiral Bidentate Phosphonites: Design, Synthesis, and Application in Catalytic Asymmetric Hydroformylation Reactions" @default.
- W2036093500 cites W117017782 @default.
- W2036093500 cites W1965724824 @default.
- W2036093500 cites W1965970498 @default.
- W2036093500 cites W1974883165 @default.
- W2036093500 cites W1985600271 @default.
- W2036093500 cites W1991237508 @default.
- W2036093500 cites W2000907737 @default.
- W2036093500 cites W2001385493 @default.
- W2036093500 cites W2011450512 @default.
- W2036093500 cites W2022427600 @default.
- W2036093500 cites W2027151283 @default.
- W2036093500 cites W2031083940 @default.
- W2036093500 cites W2032746273 @default.
- W2036093500 cites W2039939220 @default.
- W2036093500 cites W2064514926 @default.
- W2036093500 cites W2071214495 @default.
- W2036093500 cites W2072667580 @default.
- W2036093500 cites W2095418067 @default.
- W2036093500 cites W2096075269 @default.
- W2036093500 cites W2098463731 @default.
- W2036093500 cites W2102357050 @default.
- W2036093500 cites W2104352264 @default.
- W2036093500 cites W2114941977 @default.
- W2036093500 cites W2121648480 @default.
- W2036093500 cites W2122431687 @default.
- W2036093500 cites W2128433337 @default.
- W2036093500 cites W2129532734 @default.
- W2036093500 cites W2135496019 @default.
- W2036093500 cites W2137339936 @default.
- W2036093500 cites W2142050772 @default.
- W2036093500 cites W2151061345 @default.
- W2036093500 cites W2170615327 @default.
- W2036093500 cites W2333690489 @default.
- W2036093500 cites W2949995595 @default.
- W2036093500 cites W2951533567 @default.
- W2036093500 cites W2951831833 @default.
- W2036093500 cites W2953106855 @default.
- W2036093500 cites W4210559330 @default.
- W2036093500 cites W4237915111 @default.
- W2036093500 cites W4252190676 @default.
- W2036093500 cites W4252320240 @default.
- W2036093500 doi "https://doi.org/10.1002/chem.200800388" @default.
- W2036093500 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18624296" @default.
- W2036093500 hasPublicationYear "2008" @default.
- W2036093500 type Work @default.
- W2036093500 sameAs 2036093500 @default.
- W2036093500 citedByCount "58" @default.
- W2036093500 countsByYear W20360935002012 @default.
- W2036093500 countsByYear W20360935002013 @default.
- W2036093500 countsByYear W20360935002014 @default.
- W2036093500 countsByYear W20360935002015 @default.
- W2036093500 countsByYear W20360935002016 @default.
- W2036093500 countsByYear W20360935002017 @default.
- W2036093500 countsByYear W20360935002018 @default.
- W2036093500 countsByYear W20360935002019 @default.
- W2036093500 countsByYear W20360935002020 @default.
- W2036093500 countsByYear W20360935002021 @default.
- W2036093500 countsByYear W20360935002022 @default.
- W2036093500 countsByYear W20360935002023 @default.
- W2036093500 crossrefType "journal-article" @default.
- W2036093500 hasAuthorship W2036093500A5016648658 @default.
- W2036093500 hasAuthorship W2036093500A5017639833 @default.
- W2036093500 hasAuthorship W2036093500A5052267876 @default.
- W2036093500 hasAuthorship W2036093500A5057500089 @default.
- W2036093500 hasAuthorship W2036093500A5063835443 @default.
- W2036093500 hasConcept C100805817 @default.
- W2036093500 hasConcept C116569031 @default.
- W2036093500 hasConcept C146686406 @default.
- W2036093500 hasConcept C161790260 @default.
- W2036093500 hasConcept C170493617 @default.
- W2036093500 hasConcept C178516000 @default.
- W2036093500 hasConcept C178790620 @default.
- W2036093500 hasConcept C185592680 @default.
- W2036093500 hasConcept C190603991 @default.
- W2036093500 hasConcept C201194858 @default.
- W2036093500 hasConcept C21951064 @default.
- W2036093500 hasConcept C32489680 @default.
- W2036093500 hasConcept C521398313 @default.
- W2036093500 hasConcept C544153396 @default.
- W2036093500 hasConcept C55493867 @default.
- W2036093500 hasConceptScore W2036093500C100805817 @default.
- W2036093500 hasConceptScore W2036093500C116569031 @default.
- W2036093500 hasConceptScore W2036093500C146686406 @default.
- W2036093500 hasConceptScore W2036093500C161790260 @default.
- W2036093500 hasConceptScore W2036093500C170493617 @default.
- W2036093500 hasConceptScore W2036093500C178516000 @default.
- W2036093500 hasConceptScore W2036093500C178790620 @default.
- W2036093500 hasConceptScore W2036093500C185592680 @default.