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- W2036093912 abstract "The utility of a hierarchically ordered nanoporous SBA-15 architecture, comprising 270 nm macropores and 5 nm mesopores (MM-SBA-15), for the catalytic aerobic selective oxidation of sterically challenging allylic alcohols is shown. Detailed bulk and surface characterization reveals that incorporation of complementary macropores into mesoporous SBA-15 enhances the dispersion of sub 2 nm Pd nanoparticles and thus their degree of surface oxidation. Kinetic profiling reveals a relationship between nanoparticle dispersion and oxidation rate, identifying surface PdO as the catalytically active phase. Hierarchical nanoporous Pd/MM-SBA-15 outperforms mesoporous analogues in allylic alcohol selective oxidation by (i) stabilizing PdO nanoparticles and (ii) dramatically improving in-pore diffusion and access to active sites by sesquiterpenoid substrates such as farnesol and phytol." @default.
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- W2036093912 date "2013-08-19" @default.
- W2036093912 modified "2023-10-18" @default.
- W2036093912 title "Hierarchically Ordered Nanoporous Pd/SBA-15 Catalyst for the Aerobic Selective Oxidation of Sterically Challenging Allylic Alcohols" @default.
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- W2036093912 doi "https://doi.org/10.1021/cs400371a" @default.
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