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- W2036142014 abstract "Spectral changes in the P Kα and P Kβ X-ray emission lines of solid organic phosphorus compounds were measured with a two-crystal X-ray spectrometer. The P Kα line shifted to higher energies with an increasing number of oxygen atoms attached directly to a phosphorus atom. Similar shifts were found in the P Kα satellites, which were always 1.5–2.0 times larger than those of the parent Kα line. There was no simple correlation for relating the P Kβ1 shift to the phosphorus form. The P Kβ profiles of organic phosphorus seemed to be characterized by the surrounding atoms or groups. The appearance of the Kβ′ band offered possible evidence for the existence of phosphorus-oxygen bonding in the samples." @default.
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- W2036142014 date "1984-11-01" @default.
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- W2036142014 title "Chemical Effects on the X-ray<i>K</i>Emission Spectra of Phosphorus in Organic Compounds" @default.
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- W2036142014 doi "https://doi.org/10.1246/bcsj.57.3122" @default.
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