Matches in SemOpenAlex for { <https://semopenalex.org/work/W2036144583> ?p ?o ?g. }
- W2036144583 endingPage "875" @default.
- W2036144583 startingPage "866" @default.
- W2036144583 abstract "The modified Avrami model was found to accurately predict the induction time, maximum phase volume and dimensionality of crystal growth for stearic acid containing molecules when the experimental method employed measures as a function of phase volume. Four methods were examined to validate the model including: Fourier transformed infrared spectroscopy (FT-IR), differential scanning calorimetry (DSC), small deformation rheology and polarized light microscopy (PLM). PLM and FT-IR were able to detect the nucleation event prior to DSC and rheology. FT-IR and PLM provided the most accurate data due to the similarities between the experimental and fitted induction times (x0), maximal phase change (ymax) and the Avrami exponent (n). Further, the Avrami exponent, obtained from FT-IR, was sensitive to both the mode of nucleation and the dimensionality of crystal growth. Therefore, the apparent rate constants (kapp) obtained by FT-IR and PLM are useful in providing further insights into the kinetics of non-isothermal crystallization. The calculated apparent rate constants suggest a diffusion limited crystallization at slow cooling rates (i.e., below 5–7 °C min−1) and at cooling rates greater than 5–7 °C min−1, the incorporation of the gelator molecules onto the crystal lattice becomes limited by the reaction rate constant." @default.
- W2036144583 created "2016-06-24" @default.
- W2036144583 creator A5017737155 @default.
- W2036144583 creator A5053274927 @default.
- W2036144583 date "2011-01-01" @default.
- W2036144583 modified "2023-10-17" @default.
- W2036144583 title "Experimental validation of the modified Avrami model for non-isothermal crystallization conditions" @default.
- W2036144583 cites W1963540329 @default.
- W2036144583 cites W1973001784 @default.
- W2036144583 cites W1973255646 @default.
- W2036144583 cites W1974523010 @default.
- W2036144583 cites W1976672709 @default.
- W2036144583 cites W1977921368 @default.
- W2036144583 cites W1981727210 @default.
- W2036144583 cites W1982990257 @default.
- W2036144583 cites W1987280028 @default.
- W2036144583 cites W1987526319 @default.
- W2036144583 cites W1993576908 @default.
- W2036144583 cites W1996896232 @default.
- W2036144583 cites W1998681839 @default.
- W2036144583 cites W1999009670 @default.
- W2036144583 cites W2001379482 @default.
- W2036144583 cites W2002363341 @default.
- W2036144583 cites W2007219286 @default.
- W2036144583 cites W2007366926 @default.
- W2036144583 cites W2012861094 @default.
- W2036144583 cites W2014565761 @default.
- W2036144583 cites W2014912020 @default.
- W2036144583 cites W2018270339 @default.
- W2036144583 cites W2019141398 @default.
- W2036144583 cites W2024908520 @default.
- W2036144583 cites W2035362761 @default.
- W2036144583 cites W2039878600 @default.
- W2036144583 cites W2042996063 @default.
- W2036144583 cites W2051109552 @default.
- W2036144583 cites W2054914560 @default.
- W2036144583 cites W2055137886 @default.
- W2036144583 cites W2056320034 @default.
- W2036144583 cites W2059209244 @default.
- W2036144583 cites W2086091960 @default.
- W2036144583 cites W2086345888 @default.
- W2036144583 cites W2090732497 @default.
- W2036144583 cites W2091302273 @default.
- W2036144583 cites W2094920617 @default.
- W2036144583 cites W2095359303 @default.
- W2036144583 cites W2097886051 @default.
- W2036144583 cites W2101938943 @default.
- W2036144583 cites W2123744718 @default.
- W2036144583 cites W2143888156 @default.
- W2036144583 cites W2147318219 @default.
- W2036144583 cites W2154696341 @default.
- W2036144583 cites W4237495492 @default.
- W2036144583 doi "https://doi.org/10.1039/c0ce00523a" @default.
- W2036144583 hasPublicationYear "2011" @default.
- W2036144583 type Work @default.
- W2036144583 sameAs 2036144583 @default.
- W2036144583 citedByCount "40" @default.
- W2036144583 countsByYear W20361445832012 @default.
- W2036144583 countsByYear W20361445832013 @default.
- W2036144583 countsByYear W20361445832014 @default.
- W2036144583 countsByYear W20361445832015 @default.
- W2036144583 countsByYear W20361445832016 @default.
- W2036144583 countsByYear W20361445832017 @default.
- W2036144583 countsByYear W20361445832018 @default.
- W2036144583 countsByYear W20361445832019 @default.
- W2036144583 countsByYear W20361445832020 @default.
- W2036144583 countsByYear W20361445832021 @default.
- W2036144583 countsByYear W20361445832022 @default.
- W2036144583 crossrefType "journal-article" @default.
- W2036144583 hasAuthorship W2036144583A5017737155 @default.
- W2036144583 hasAuthorship W2036144583A5053274927 @default.
- W2036144583 hasConcept C110530677 @default.
- W2036144583 hasConcept C121332964 @default.
- W2036144583 hasConcept C127413603 @default.
- W2036144583 hasConcept C133347239 @default.
- W2036144583 hasConcept C148898269 @default.
- W2036144583 hasConcept C160892712 @default.
- W2036144583 hasConcept C192562407 @default.
- W2036144583 hasConcept C199360897 @default.
- W2036144583 hasConcept C200990466 @default.
- W2036144583 hasConcept C203036418 @default.
- W2036144583 hasConcept C204774569 @default.
- W2036144583 hasConcept C2781285689 @default.
- W2036144583 hasConcept C39519442 @default.
- W2036144583 hasConcept C41008148 @default.
- W2036144583 hasConcept C42360764 @default.
- W2036144583 hasConcept C61048295 @default.
- W2036144583 hasConcept C62520636 @default.
- W2036144583 hasConcept C93391505 @default.
- W2036144583 hasConcept C97355855 @default.
- W2036144583 hasConceptScore W2036144583C110530677 @default.
- W2036144583 hasConceptScore W2036144583C121332964 @default.
- W2036144583 hasConceptScore W2036144583C127413603 @default.
- W2036144583 hasConceptScore W2036144583C133347239 @default.
- W2036144583 hasConceptScore W2036144583C148898269 @default.
- W2036144583 hasConceptScore W2036144583C160892712 @default.
- W2036144583 hasConceptScore W2036144583C192562407 @default.
- W2036144583 hasConceptScore W2036144583C199360897 @default.